单词 | norpinic acid |
释义 | > as lemmasnorpinic acid norpinic acid n. Brit. /nɔːˌpɪnɪk ˈasɪd/ , U.S. /nɔrˌpɪnɪk ˈæsəd/ a crystalline dicarboxylic acid, C8H12O4, existing in cis and trans isomers and differing from pinic acid in having a carboxyl group attached to the cyclobutane ring in place of a carboxymethyl group.ΘΚΠ the world > matter > chemistry > organic chemistry > organic acids > [noun] > dicarboxylic acids > miscellaneous others suberic acid1796 oxalovinic acid1838 citraconic acid1840 melanic acid1840 citramalic acid1864 citratartaric acid1864 isophthalic acid1870 methylmalonic acid1889 norpinic acid1909 naphthalic acid1920 1909 Jrnl. Chem. Soc. 95 1170 Our experiments have, however, shown that this ring, in norpinic acid, exhibits quite unusual stability. 1932 J. L. Simonsen Terpenes II. iii. 129 By the action of dilute hydrochloric acid at 180° [on the cis-isomer], an equilibrium mixture of cis- and trans-norpinic acids is obtained. 1960 A. R. Pinder Chem. of Terpenes v. 91 The molecular formula and properties of norpinic acid suggested it was derived from cyclobutane. < as lemmas |
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