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单词 excimer
释义

excimern.

/ˈɛksɪmə/
Etymology: < exci- (in excited adj.)+ dimer n.
Chemistry.
An exciplex; spec. one formed from two identical atoms or molecules.
ΘΚΠ
the world > matter > chemistry > atomic chemistry > [noun] > molecules > other molecules
supermolecule1834
open chain1880
excimer1960
exciplex1966
superatom1972
1960 Stevens & Hutton in Nature 25 June 1046/2 These properties of the collisionally formed excited dimer which has virtually the lifetime of a triplet state and the multiplicity of a singlet state are those of an ideal sensitizer…We suggest the term ‘excimer’ be used to distinguish it from the short-lived dimer excited directly in solutions exhibiting an absorption spectrum dependent on concentration.
1962 Stevens & Hutton in Nature 6 Oct. 34/2 The difference by a factor of 2 between the excimer components of the observed mixture spectrum Z and (A+B) is therefore attributed to ‘mixed excimers’ (AB)*.
1972 C. H. DePuy & O. L. Chapman Molecular Reactions & Photochem. iv. 53 These dimers may be formed via an excimer..derived from the 3(π, π*) cyclohexenone and a molecule of ground state cyclohexenone.
1979 Mataga & Ottolenghi in R. Foster Molecular Assoc. II. i. 2 Excimer formation has now been observed for a multitude of aromatic hydrocarbons and their derivatives in fluid solutions. Excimers are also known in crystals and in low-temperature rigid solvents.

Compounds

Special combinations.
excimer laser n. a laser in which an excimer is used as the excited state for stimulated emission.
ΘΚΠ
the world > matter > physics > electromagnetic radiation > light > laser > [noun]
laser1960
ruby laser1960
laser gun1961
injection laser1963
phaser1966
dye laser1967
excimer laser1973
laser pen1981
1973 S. E. Harris Investigation Laser Dynamics (NASA Rep. CR-136024) Studies of the sodium-xenon excimer laser.
1985 Time 11 Mar. 21/2 Excimer lasers..produce beams of short wavelengths that could destroy a missile by focusing on it for only a second.
1986 New Scientist 13 Nov. 44/1 The excimer laser..emits ultraviolet light that cuts and marks materials without damaging them with heat…They are gas lasers that emit light when a halogen atom and a rare gas atom combine temporarily.
This entry has not yet been fully updated (first published 1989; most recently modified version published online September 2018).
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n.1960
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