单词 | trinitro- |
释义 | trinitro-comb. form Chemistry. 1. A formative denoting that three nitro-groups, NO2, have replaced three hydrogen atoms in the substance designated by the rest of the name, the nitrogen atoms being directly joined to carbon atoms; e.g. trinitrophenol n. or picric acid, C6H2(NO2)3(OH), in which three H atoms of phenol have been replaced by three NO2 groups, the N atoms directly joined to three C atoms. So trinitrocresol n. C6H(CH3)(OH)(NO2)3, from cresol. trinitronaphthalene n. C10H5(NO2)3 from naphthalene, C10H8, etc. Also attributive, as tri-nitro carbolic acid. ΚΠ 1851 Q. Jrnl. Chem. Soc. 3 75 A third compound is formed, in which 3 eq. of hydrogen are replaced by hyponitric acid: this is Trinitranisol. 1869 H. E. Roscoe Lessons Elem. Chem. (new ed.) xxxix. 381 Tri-nitro-phenol [1866, xxxix. 336 tri-nitro carbolic acid], or picric acid, is a bright yellow crystalline body. 2. In earlier nomenclature, trinitro- included cases in which the nitrogen atoms of the NO2 groups were attached by oxygen atoms to the carbon atoms of the substance designated by the rest of the name; such compounds are now called trinitrates (see trinitrate n.); e.g. triˌnitroˈglycerin n. C3H5(O.NO2)3 (also trinitrin n.), now called glyceryl trinitrate. trinitro-cellulose n. or gun-cotton, a powerful explosive, considered to be {C6H7O2(O.NO2)3}x, derived from cellulose, {C6H10O5}x, by replacement of OH groups by O.NO2 groups of nitric acid, HO.NO2, the molecule being some unknown multiple of the formula. (See also quot. 1910.) ΘΚΠ society > occupation and work > materials > derived or manufactured material > explosive material > [noun] > other specific explosives powdera1393 gunpowder1411 saltpetre1501 petre1586 halinitre1608 sal-prunella1664 petre-salt1708 xyloidin1838 gun-cotton1846 pyroxyle1847 pyroxylin1847 pyroglycerin1850 xylidine1850 nitroglycerine1852 gun-sawdust1853 picrate1854 trinitroglycerin1864 nitroleum1866 trinitrin1866 dynamite1867 giant-powder1872 dualin1874 fulgurite1874 rendrock1874 glyoxilin1875 lithofracteur1875 trinitro-cellulose1875 white gunpowder1875 gelatin1878 cotton-powder1879 vigorite1879 blasting gelatine1881 Hercules powder1881 saxifragine1881 tonite1881 dynamogen1882 forcite1883 haloxylin1883 jelly powdera1884 nitro-gelatinea1884 panclastite1883 potentite1883 sebastinea1884 kolloxylin1884 hellhoffite1885 rackarock1885 securite1886 kinetite1887 roburite1887 carbo-dynamite1888 fortis1889 gelatine dynamite1889 gelignite1889 seranine1889 straw-dynamite1889 carbonite1890 amberite1891 nitro powder1892 Schnebelite1893 westfalite1894 thorite1899 soup1902 ammonal1903 cheddite1908 trinitrotoluene1908 Samsonite1909 tolite1909 trinitrotoluol1910 trotyl1910 glyceryl trinitrate1912 T.N.T.1915 nitro1916 amatol1918 cyclonite1923 hexogen1923 lox1923 pentaerythritol tetranitrate1923 hexite1931 aurantia1940 jelly1941 RDX1941 1864 Mills in Jrnl. Chem. Soc. XVII. 158 I prepared trinitro-glycerin for this purpose. 1866 H. E. Roscoe Lessons Elem. Chem. xxxvi. 316 If the nitric acid employed to act on glycerine be concentrated, a new compound called Trinitrine, or Trinitro-glycerine, is formed. 1875 H. C. Wood Treat. Therapeutics (1879) 589 The true explosive gun-cotton, that which is alone adapted for gunnery, is tri~nitrocellulose. 1897 Daily News 9 Feb. 7/4 Mr. Maxim..took the two most powerful smokeless explosives, nitro~glycerine and tri-nitro-cellulose. He mixed them by dissolving them in something which would dissolve both. 1910 A. J. Walker & O. E. Mott tr. A. F. Holleman Text-bk. Org. Chem. (ed. 3) 293 In the nitration of cellulose the final product is trinitro-oxy~cellulose..the formation of the trinitro-compound is accompanied by oxidation of the cellulose... (C24H40O21)x. This entry has not yet been fully updated (first published 1914; most recently modified version published online March 2022). < comb. form1851 |
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