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单词 parabanic
释义

parabanicadj.

Brit. /ˌparəˈbanɪk/, U.S. /ˌpɛrəˈbænɪk/
Origin: A borrowing from German, combined with an English element. Etymons: German Parabansäure , -ic suffix.
Etymology: < paraban- (in German Parabansäure parabanic acid (F. Wöhler & J. Liebig 1838, in Ann. der Pharm. 26 285)) + -ic suffix.The term German Parabansäure was introduced without any explanation of its formation, but as Wöhler and Liebig had made parabanic acid by a reaction in which they expected to obtain alloxan (which they also named), it is probably that para- was used in the sense ‘instead of’, ‘opposed to’ (compare para- prefix1 3a), the ending being that of allox-an , -anic (see alloxan n.), and the b merely euphonic. It has also been suggested that the b is a residue of carb-, and that the term was formed to express parallelism of constitution to urea or carbamide, CO(NH2)2, and to alloxan, (CO)4(NH)2; however, it was not until the 1850s that the identity of urea and carbamide was realized.
Chemistry.
parabanic acid n. a crystalline heterocyclic compound with acidic properties, (CO)3(NH)2, first made by oxidizing uric acid. Also called oxalylurea.
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the world > matter > chemistry > organic chemistry > acids obtained from animals > [noun] > in urine > uric acid > derivatives of
parabanic acid1838
paraban1842
1838 Brit. Ann. & Epitome Progress Sci. 1839 380 When uric acid is dissolved in eight parts of concentrated nitric acid, and evaporated, after the gases have ceased to escape, at a certain point of the concentration six-sided prisms fall, which are parabanic acid.
1888 I. Remsen Introd. Study Compounds of Carbon 203 Parabanic acid is formed by boiling uric acid with strong nitric acid and other oxidizing agents.
1967 I. L. Finar Org. Chem. (ed. 5) xvi. 419 Dicarboxylic acids react with urea in the presence of phosphoryl chlorides to form cyclic ureides; e.g., oxalic acid forms parabanic acid (oxalylurea).
1995 Neuroreport 6 1816/2 Allantoin and parabanic acid..were analysed by HPLC with UV detection (205 nm).
This entry has been updated (OED Third Edition, June 2005; most recently modified version published online March 2022).
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adj.1838
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