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单词 metacetone
释义

metacetonen.

Origin: Formed within English, by derivation; modelled on a French lexical item. Etymons: meta- prefix, acetone n.
Etymology: < meta- prefix + acetone n., after French métacétone (E. Frémy 1835, in Ann. de chim. et de physique 59 10). N.E.D. (1906) gives the pronunciation as (metæ·sĭtōun) /mɛˈtæsɪtəʊn/.
Chemistry. Obsolete.
A colourless oily liquid produced, together with acetone, by distilling a mixture of cane sugar and lime.Metacetone was identified by some chemists with diethyl ketone (formerly called propione), but it was later thought to be a mixture of organic compounds including propionaldehyde (see quot. 1889).
ΚΠ
1838 T. Thomson Chem. Org. Bodies 364 M. Fremy discovered that when 1 part of sugar is intimately mixed with 8 parts of unslacked lime, and distilled, the product consists of two liquids, one of which is acetone, and to the other he has given the name of metacetone.
1844 G. Fownes Man. Elem. Chem. 409 M. Frémy calls this substance metacetone; it contains C6H50, and is consequently isomeric with Dr. Kane's oxide of mesityle.
1851 Jrnl. Chem. Soc. 4 3 Further researches are required in order to show whether Frémy's metacetone is merely a mixture containing propione as one of its constituents, or whether it be a definite compound.
1852 W. Gregory Handbk. Org. Chem. (ed. 3) 228 It [sc. propione] was formerly called metacetone.
1877 H. Watts Fownes's Man. Chem. (ed. 12) II. 263 An isomeric compound, called Metacetone, is formed by distilling sugar with lime; it is a liquid boiling at 84°.
1889 Jrnl. Chem. Soc. 55 487 An examination of the products obtained by distilling sugar with lime under the conditions described by Gottlieb shows that metacetone does not exist, and that Fremy's substance is a mixture of propaldehyde, dimethylfurfuran, and a fluid hydrocarbon-like compound.
This entry has been updated (OED Third Edition, December 2001; most recently modified version published online December 2019).
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