单词 | lactim |
释义 | lactimn. Chemistry. Any of the class of cyclic imines which are isomers of the lactams and characterized by the group N:C(OH) as part of a ring. ΚΠ 1883 Jrnl. Chem. Soc. 44 202 The authors propose the name lactam for bodies formed like acetylisatin, and lactim for those formed like isatin. 1936 L. J. Desha Org. Chem. xxvi. 522 Lactam-lactim tautomerism involves the shift of a hydrogen atom from nitrogen to oxygen and vice versa. 1951 I. L. Finar Org. Chem. I. xxx. 619 Isatin exists in two forms, the term ψ-isatin being applied to the lactam form I, and isatin to the lactim form II. 1971 Canad. Jrnl. Chem. 49 2612 Investigation showed the free lactim ether to be a probable intermediate in this reaction. This entry has not yet been fully updated (first published 1976; most recently modified version published online June 2021). < n.1883 |
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