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单词 tridentate
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tridentate

The coordination modes for 2,5-dimethylbenzenedicarboxylates are bis(bidentate) or bidentate-tridentate.The organic anions act as tridentate chelating ligands.The metal atoms are connected via the bis-tridentate ligand into a binuclear structure.The tridentate ligands were prepared from 2-phenylimidazole-4-carboxylic acid and chiral amines.Synthetic routes to four new tridentate ligands with large cavities have been developed.Copper and zinc complexes of the investigated tridentate ligands have been proposed.The sulfonic group prefers a tridentate binding.Two crystallographically different tpht anions are coordinated as tridentate and hexadentate ligands forming two-dimensional layers.Each completely deprotonated 4-hydroxypyridine-2,6-dicarboxylic acid molecule assumes a tridentate chelating coordination mode.The benzoate ligands adopt two different coordination modes, acting as bidentate and bridging tridentate ligands.
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更新时间:2025/1/8 10:57:52