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单词 zeldovich reaction
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Zeldovich reaction
attributive. Designating a reaction mechanism proposed by Zeldovich for the oxidation of nitrogen to nitric oxide during combustion; of or relating to this mechanism. Esp. in Zeldovich mechanism, Zeldovich reaction.The mechanism involves a two-step chain process: O + N2 → NO + N; N + O2 → NO + O.
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Zeldovich1956
Woodward–Hoffmann1968
1956 Appl. Mech. Reviews 9 507/2 In the Zeldovich chain mechanism hypothesis, it is assumed that oxygen dissociation reaches equilibrium in a time small compared with that for the formation of nitric oxide.
1973 S. J. Williamson Fund. Air Pollution x. 298 The formation of NO occurs primarily through two simultaneous reactions known as the Zeldovich mechanism .
1982 Sci. Amer. Feb. 94/1 At temperatures low enough to suppress the Zeldovich reactions other reactions still generate nitric oxide.
2000 A. M. Dean & J. W. Bozzelli in W. C. Gardiner Gas Phase Combustion Chem. ii. 127 One must describe the kinetics of flame front chemistry properly in order to predict Zeldovich NO production accurately.
2011 Proc. Combustion Inst. 33 11/1 Accurate rates for the Zeldovich reactions are essential to accurate simulations.
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