单词 | rhodizonic |
释义 | rhodizonicadj. Chemistry. rhodizonic acid n. a crystalline dibasic acid whose salts are used in solution as analytic reagents to detect certain metals, esp. barium, which form red or brown precipitates.Systematic name: 5,6-dihydroxycyclohex-5-ene-1,2,3,4-tetrone; C6H2O6.In quot. 1862 referring to a different substance. ΘΚΠ the world > matter > chemistry > chemical substances > acids > [noun] > acids-named > containing metal ion perlate acid1785 permanganic acid1836 rhodizonic acid1838 1838 Brit. Ann. & Epitome Progress Sci. 1839 346 Rhodizoic [sic] acid may be isolated from the potash salt. 1842 T. Graham Elements Chem. iii. viii. 934 Rhodizonic Acid..was first observed by L. Gmelin, and recognised as a new acid by Heller. 1862 Amer. Jrnl. Sci. 83 274 The rhodizonic acid obtained by Brodie, by the action of absolute alcohol on the compound of carbonic oxyd and potassium, has probably the formula C20O16K6 or C10O8K3. 1916 C. A. Mitchell Vinegar ix. 154 Tests of identity have been based upon the oxidation of the sugar into a quinonic compound, rhodizonic acid, some of the salts of which are of a bright red colour. 1955 J. C. Giblin Qualitative & Volumetric Anal. (ed. 2) iii. 77 In this reaction, the barium or strontium salts of rhodizonic acid are first formed as brown ppts. 1991 Arch. Environmental Contamination & Toxicol. 20 423 Lead was leached from ceramic ware with citric acid and identified by rhodizonic acid in this quick, qualitative test. This entry has been updated (OED Third Edition, June 2010; most recently modified version published online March 2022). < adj.1838 |
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