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单词 retro-ene reaction
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retro-ene reaction
4. Chemistry. Prefixed to the names of (organic) reaction types in order to designate the equivalent processes taking place in reverse, as retro-ene reaction, retro-pinacol rearrangement, etc.
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1921 Jrnl. Chem. Soc. 120 i. 233 (heading) Some retropinacolic transpositions.
1950 Jrnl. Amer. Chem. Soc. 72 118/1 This, when treated with acid, underwent the retro-pinacol rearrangement to give the α,β-dimethyl-4,4′-stilbenediamine.
1968 Jrnl. Amer. Chem. Soc. 90 4730/1 The product from..a retro-ene reaction.
1972 C. H. DePuy & O. L. Chapman Molecular Reactions & Photochem. vii. 140 Retro-Diels-Alder reactions may be carried out in the vapor phase in the absence of all solvents and catalysts.
1977 J. March Adv. Org. Chem. (ed. 2) xviii. 980 Terpene chemists call the migration of a methyl group the Nametkin rearrangement. The term retropinacol rearrangement is often applied to some or all of these.
2001 Proc. National Acad. Sci. U.S.A. 98 432/1 A nucleophilic addition of the alcohol..followed by an intramolecular retro-ene reaction.
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