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单词 belousov-zhabotinsky reaction
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Belousov-Zhabotinsky reaction
attributive. Designating any of a class of reactions involving bromine and an acid in which a solution periodically oscillates between two colours as a result of the reduction and oxidation of a catalyst; esp. as Belousov-Zhabotinsky reaction. Abbreviated BZ.A typical reaction of this type is the oxidation of malonic acid by acidic bromate, catalysed by a cerium salt. In this reaction, cerium( iv) ions are reduced by malonic acid to cerium( iii) ions, which are then oxidized back to cerium( iv) ions by bromate ions. The colour of the solution changes from colourless (in the presence of cerium( iv)) to yellow (in the presence of cerium( iii)), and back again.
ΚΠ
1972 Jrnl. Chem. Educ. 49 310/1 The Belousov reaction itself, as well as the four component reactions in its simplified mechanism, do indeed fulfill the requirements for undamped oscillations to occur.]
1973 Jrnl. Chem. Physics 59 6277/1 Among the few chemical reactions known to exhibit limit cycles, two have already shown dissipative structues: the Belousov-Zhabotinskii reaction and the glycolytic system.
1983 Sci. Amer. Mar. 98/1 Zhabotinsky..modified Belousov's recipe somewhat (for example by replacing the cerium reagent with an iron reagent that gave a more distinctive red-blue colour change) and began a systematic study of the reaction, which is now called the BZ (for Belousov-Zhabotinsky) reaction.
1995 New Scientist 18 Feb. 18/2 The..team studied an example from chemistry called the Belousov-Zhabotinsky (BZ) reaction, in which malonic acid is converted to carbon dioxide by reacting with bromate.
2009 R. C. Desai & R. Kapral Dynamics Self-organized & Self-assembled Struct. xxiv. 231 An example of an expanding and buckling scroll ring in the Belousov–Zhabotinsky reaction is shown.
extracted from Belousov-Zhabotinskyn.
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