单词 | pinacoline |
释义 | pinacolinen. Chemistry. = pinacolone n. ΘΚΠ the world > matter > chemistry > organic chemistry > organic bases > [noun] creatine1835 cystine1843 ammeline1846 creatinine1847 thialdine1847 toluidine1850 pyrrole base1853 parapicoline1857 pinacoline1866 xanthinine1868 choline1869 xanthocreatinine1887 xanthocreatine1891 Schiff base1892 tar base1921 thiocholine1929 the world > matter > chemistry > organic chemistry > ketones > [noun] > pinacolin pinacoline1866 pinacolone1920 1866 H. Watts Dict. Chem. IV. 647 Pinacolin,..an oily body produced by the dehydration of pinacone. 1884 H. E. Roscoe & C. Schorlemmer Treat. Chem. III. ii. 12 The pinacones decompose very readily into water and the ketones, to which the name of pinacolines is given. 1936 L. J. Desha Org. Chem. 538 The pinacol rearrangement is irreversible in the sense that pinacolins do not change into pinacols. 1973 B. J. Hazzard tr. Organicum 587 In textbooks, the dihydric alcohol here termed pinacol is often called pinacone and the ketone produced by the rearrangement pinacoline. 1995 Jrnl. Amer. Chem. Soc. 117 876 1,2-Phenyl migrations in a pinacolin rearrangement. This entry has been updated (OED Third Edition, June 2006; most recently modified version published online March 2022). < |
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