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单词 mercaptan
释义

mercaptann.

Brit. /məːˈkapt(ə)n/, /məːˈkaptan/, U.S. /mərˈkæpˌtæn/, /mərˈkæpt(ə)n/
Origin: A borrowing from German. Etymon: German Mercaptan.
Etymology: < German Mercaptan (W. C. Zeise 1834, in Ann. der Physik u. Chem. 31 378) < mer- (in post-classical Latin mercurius : see mercury n.) + captan- (in classical Latin captāns , present participle of captāre to take, seize: see captate v.): Zeise explains the formation as follows ‘Mercaptan (d.h. Corpus mercurium captans)’. Compare mercaptide n.
Chemistry.
Any of a series of organic compounds containing a sulphydryl group, SH, many of which have a strong, unpleasant odour; a thioalcohol, a thiol.
ΚΠ
1835 R. D. Thomson in Rec. Gen. Sci. 1 110 Mercaptan when obtained pure from the mercaptide of mercury, is colourless, with a smell of assafœtida.
1865 H. Watts Dict. Chem. III. 882 Mercaptans, sulphydrates of the alcohol-radicles.
1889 Pall Mall Gaz. 26 Apr. 2/3 Sulfonal is a ‘hypnotic’, which is free from the incalculable dangers of the ‘narcotic’ remedies such as the opiates and chloral. It is obtained..from the combination of ethyl mercaptan and acetone by the process of oxidation.
1913 V. B. Lewes Oil Fuel 25 The sulphur in oil is fully accounted for by sulphates..becoming reduced to sulphide by the vegetable remains, and yielding mercaptans, thiophenes and sulphides.
1955 Sci. News Let. 1 Jan. 4/1 When gasoline is separated from petroleum, there are often offensive odors in the solution caused by sulfur compounds called mercaptans.
1986 New Yorker 17 Mar. 62/2 The mercaptan concentrate is stored in a tank in the center of the station grounds.
1991 Lancet 21 Dec. 1551/2 Hypermethioninaemia has persisted and the child has an unpleasant odour with high blood concentrations of mercaptans.
This entry has been updated (OED Third Edition, September 2001; most recently modified version published online March 2022).
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