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单词 ethynyl
释义

ethynyln.

Brit. /ᵻˈθʌɪnɪl/, /ᵻˈθʌɪnʌɪl/, /ˈɛθᵻnɪl/, U.S. /ɛˈθaɪn(ə)l/, /ˈɛθəˌnɪl/
Forms: 1800s– ethinyl, 1900s– ethynyl.
Origin: Formed within English, by derivation; perhaps modelled on a French lexical item, or perhaps modelled on a German lexical item. Etymons: ethyne n., -yl suffix.
Etymology: < ethyne n. (compare forms at that entry) + -yl suffix, after French éthinyle (1866) or its etymon German Aethinyl (A. W. Hofmann 1866, in Monatsbericht der Königl. Preuss. Akad. der Wissenschaften zu Berlin, 1865 653; now usually Ethynyl).
Chemistry.
The unsaturated hydrocarbon radical —C≡CH, derived from ethyne (acetylene). Usually attributive.See also ethinyloestradiol n.
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the world > matter > chemistry > organic chemistry > hydrocarbons > [noun] > hydrocarbon radicals > named, by number of carbon atoms > two
ethynyl1867
acetenyl1870
ethanoyl1894
the world > matter > chemistry > organic chemistry > hydrocarbons > [adjective] > hydrocarbon radicals > by number of carbon atoms > two
ethanoic acid1892
ethynyl1933
1867 A. W. Hofmann in Proc. Royal Soc. 1866–7 15 58 Ethinyl, (C2 H)v.
1881 W. R. Hodgkinson & A. J. Greenaway tr. J. Wislicenus Strecker's Short Text-bk. Org. Chem. 452 At present compounds of the nucleus =CH.C≡, ethinyl [Ger. Aethinyl], and some aldehyde acids richer in carbon are known.
1933 Jrnl. Amer. Chem. Soc. 55 3911 4-ethenyl-5-ethynyl-4-octene.
1951 A. Grollman Pharmacol. & Therapeutics xxvi. 579 Its [sc. estradiol's] ethinyl derivative is also more active orally than is the parent substance.
1975 Physics Bull. Feb. 53/1 Space chemistry continues to grow apace with the discovery of increasing numbers of small molecules in interstellar space. The most recent is the ethynyl radical, C2H.
2006 J. M. Hornback Org. Chem. (Internat. Student ed.) xxviii. 1204 The incorporation of an ethynyl group at position 17 increased the oral activity of these drugs.
This entry has been updated (OED Third Edition, March 2014; most recently modified version published online March 2022).
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n.1867
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