enantiomericadj.

Brit.

/ᵻˌnantɪə(ʊ)ˈmɛrɪk/,

/ɛˌnantɪə(ʊ)ˈmɛrɪk/, U.S.

/əˌnæntioʊˈmɛrɪk/,

/ɛˌnæntioʊˈmɛrɪk/

Origin: Formed within English, by derivation. Etymons: enantiomer n., -ic suffix.

Etymology: < enantiomer n. + -ic suffix.

Chemistry.

Of the nature of an enantiomer; of or relating to enantiomers.

ΚΠ

1933 Jrnl. Amer. Chem. Soc. 55 164 The enantiomeric levo tartrate likewise does not deviate in this respect from dextro tartrate.

1959 D. J. Cram & G. S. Hammond Org. Chem. vi. 127 Compounds XIa and XIb, which are also enantiomeric, are incapable of interconversion.

1976 Science 2 July 24/2 The maintenance of enantiomeric purity..is less puzzling but nevertheless still challenging to chemists.

2001 Guardian 4 Oct. (Online section) 11/5 Propoxyphen, a synthetic version of opium, is a painkiller in one enantiomeric form and a cough relief drug in the other.

Compounds

enantiomeric excess n. the excess of one enantiomer over another in a mixture, typically expressed as a percentage; (also) the fact of a mixture containing one enantiomer in excess of another.

ΚΠ

1953 Jrnl. Org. Chem. 18 436 The two diastereomeric coordination complexes would be expected to compete at different rates for a deficiency of the isocyanate..to give an enantiomeric excess of one anilide over the other.

1974 Science 31 May 943/3 The percent of enantiomeric excess that must be achieved to make an asymmetric synthesis useful varies with each case.

1999 Chem. in Brit. Mar. 32/2 Automated chiral GC methods allowed researchers to determine enantiomeric excesses.

Derivatives

eˌnantioˈmerically adv.

ΚΠ

1947 Jrnl. Amer. Chem. Soc. 69 700/1 A suspension of 216g. (1 mole) of yellow mercuric oxide and 1 mole of a l(+)-lactic acid (85% solution, enantiomerically 96% pure) was shaken in the dark for thirty minutes to complete solution.

2000 W. Cabri & R. Di Fabio From Bench to Market ix. 197 Enantiomerically pure tertiary alcohol.

This is a new entry (OED Third Edition, June 2011; most recently modified version published online March 2022).

单词	enantiomeric
释义	enantiomericadj. Brit. /ᵻˌnantɪə(ʊ)ˈmɛrɪk/, /ɛˌnantɪə(ʊ)ˈmɛrɪk/, U.S. /əˌnæntioʊˈmɛrɪk/, /ɛˌnæntioʊˈmɛrɪk/ Origin: Formed within English, by derivation. Etymons: enantiomer n., -ic suffix. Etymology: < enantiomer n. + -ic suffix. Chemistry. Of the nature of an enantiomer; of or relating to enantiomers. ΚΠ 1933 Jrnl. Amer. Chem. Soc. 55 164 The enantiomeric levo tartrate likewise does not deviate in this respect from dextro tartrate. 1959 D. J. Cram & G. S. Hammond Org. Chem. vi. 127 Compounds XIa and XIb, which are also enantiomeric, are incapable of interconversion. 1976 Science 2 July 24/2 The maintenance of enantiomeric purity..is less puzzling but nevertheless still challenging to chemists. 2001 Guardian 4 Oct. (Online section) 11/5 Propoxyphen, a synthetic version of opium, is a painkiller in one enantiomeric form and a cough relief drug in the other. Compounds enantiomeric excess n. the excess of one enantiomer over another in a mixture, typically expressed as a percentage; (also) the fact of a mixture containing one enantiomer in excess of another. ΚΠ 1953 Jrnl. Org. Chem. 18 436 The two diastereomeric coordination complexes would be expected to compete at different rates for a deficiency of the isocyanate..to give an enantiomeric excess of one anilide over the other. 1974 Science 31 May 943/3 The percent of enantiomeric excess that must be achieved to make an asymmetric synthesis useful varies with each case. 1999 Chem. in Brit. Mar. 32/2 Automated chiral GC methods allowed researchers to determine enantiomeric excesses. Derivatives eˌnantioˈmerically adv. ΚΠ 1947 Jrnl. Amer. Chem. Soc. 69 700/1 A suspension of 216g. (1 mole) of yellow mercuric oxide and 1 mole of a l(+)-lactic acid (85% solution, enantiomerically 96% pure) was shaken in the dark for thirty minutes to complete solution. 2000 W. Cabri & R. Di Fabio From Bench to Market ix. 197 Enantiomerically pure tertiary alcohol. This is a new entry (OED Third Edition, June 2011; most recently modified version published online March 2022). < adj.1933
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