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单词 cyclopentadiene
释义

cyclopentadienen.

Brit. /ˌsʌɪkləʊpɛntəˈdʌɪiːn/, U.S. /ˈsaɪkloʊˌpɛn(t)əˈdaɪˌin/
Origin: Formed within English, by derivation; modelled on a German lexical item. Etymons: cyclo- comb. form, penta- comb. form, di- prefix1, -ene comb. form.
Etymology: < cyclo- comb. form + penta- comb. form + di- prefix1 + -ene comb. form, after German Cyclopentadiën (G. Kraemer & A. Spilker 1896, in Berichte der Deutsch. chem. Ges. 29 554).
Chemistry.
A liquid unsaturated cyclic hydrocarbon, C5H6, that is formed as a by-product of the cracking of petroleum, readily reacts to produce a solid dimer, and is used in the manufacture of synthetic resins and in organic syntheses. Also: a substituted derivative of this compound. Cf. cyclopentadienyl n. Unlike the cyclopentadienyl anion, the cyclopentadiene molecule is non-planar and not aromatic.
ΚΠ
1896 Jrnl. Chem. Soc. 70 i. 289 The authors refer to it as the cyclopentadiene of coal tar.
1922 J. J. Sudborough Bernthsen's Text-bk. Org. Chem. (new ed.) xxxiii. 541 Although the five-membered heterocyclic unsaturated compounds resemble benzene, the unsaturated carbocyclic compound cyclopentadiene does not.
1959 E. P. Stevenson in H. Jarrett Sci. & Resources iv. 126 A new fuel additive, not yet ready for commercial use, is based on manganese and cyclopentadiene.
1992 Chemosphere 24 525 The organic compounds identified from the thermal decomposition of 1,2-dichlorobenzene were unsaturated chlorinated aliphatic hydrocarbons, chlorinated cyclopentadienes, [etc.].
This is a new entry (OED Third Edition, December 2005; most recently modified version published online March 2022).
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n.1896
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