单词 | aldolization |
释义 | aldolizationn. Chemistry. Conversion of an aldehyde or ketone to an aldol or a structurally related molecule. Cf. aldol condensation n. at aldol n. Compounds. ΘΚΠ the world > matter > chemistry > chemical reactions or processes > [noun] > chemical reactions (general) > specific hydrolysis1880 aldol condensation1886 aldol reaction1888 aldolization1898 base exchange1912 acidolysis1930 1898 Trans. Royal Soc. Canada 4 iii. 107 Even under the most favourable conditions aldolization in this compound does not take place. 1938 C. F. H. Allen & A. H. Blatt in H. Gilman Org. Chem. I. vi. 569 Schiff's bases add organic compounds containing an active α-hydrogen atom by a process which is analogous to aldolization. 1975 Nature 25 Sept. 303/2 Although the kinetics of aldolisation reactions have been studied, no observations have been reported concerning the effect of oxygen on their rates and kinetics. 2001 R. A. Sheldon & H. van Bekkum Fine Chemicals through Heterogeneous Catalysis vii. 327 One of the difficulties in performing aldolization is the reversibility of the reaction, which limits the equilibrium conversion. This entry has been updated (OED Third Edition, September 2012; most recently modified version published online December 2021). < |
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