释义 |
Slater3 Physics.|ˈsleɪtə(r)| [The name of John C. Slater (1900–76), U.S. physicist.] Slater determinant: a determinant which expresses the total wave function of an atom and is totally anti-symmetric with respect to an interchange of electrons, the elements being single-electron wave functions. Described by Slater in Physical Rev. (1929) XXXIV. 1293.
1952Jrnl. Chem. Physics XX. 769/1 The wave function of the 3Eu- state is {vb}ϕ0ϕ0ϕ1ϕ1ϕ-1ϕ-2{vb} or {vb}ϕ0ϕ0ϕ-1ϕ-1ϕ1ϕ2{vb}, where {vb}{ddd}{vb} means a Slater determinant, and the spin is assumed to be suitable for each state. 1964L. Wilets Theories Nucl. Fission iv. 56 A Slater determinant of plane waves replaces the highly correlated true wave function. 1976Nature 28 Oct. 804/2 Such determinants have ever since been known as Slater determinants and have found applications in many fields. |