| 释义 |
perbromic, a. Chem.|pɜːˈbrəʊmɪk|
[f. per-1 5 b + bromic a.]
perbromic acid: HBrO4, a strong acid with oxidizing properties that was first prepared in 1968. Hence perˈbromate, a salt of this acid.
Claims for the preparation of the acid and its salts in the 19th c. proved to be mistaken.
1864Chem. News 30 Apr. 205/2 Perbromic acid has been fruitlessly investigated by many chemists, but M. Kaemmerer has obtained it in the most simple manner by treating perchloric acid with bromine. Ibid. Perbromate of potash is more soluble than the perchlorate, and less so than the bromate. 1866Roscoe Elem. Chem. 102 Perbromic Acid, or Hydric Perbromate..obtained by the action of bromine upon perchloric acid. 1912Chem. News 2 Aug. 50/1 It seems that it must be finally concluded that perbromic acid and its salts are incapable of existence. 1968Jrnl. Amer. Chem. Soc. XC. 1900/2 These results indicated the formation of a relatively unreactive perbromate ion and suggested that a determined effort might lead to the preparation of macro amounts of perbromates. Ibid. 1901/2 As expected, the volatility of perbromic acid is less than that of perchloric acid. 1973Downs & Adams in J. C. Bailar et al. Comprehensive Inorg. Chem. II. xxvi. 1451 First obtained in studies of the β-decay of 83SeO42-, perbromates are also formed in the γ-radiolysis of crystalline bromates. Ibid. 1452 On very rapid evaporation, crystallization of perbromic acid solutions occurs (possibly to give HBrO4, 2H2O) just before decomposition sets in. |