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单词 cupellation
释义

cupellation

enUK

cu·pel·la·tion

C0806900 (kyo͞o′pə-lā′shən)n. A refining process for nonoxidizing metals, such as silver and gold, in which a metallic mixture is oxidized at high temperatures and base metals are separated by absorption into the walls of a cupel.

cupellation

(ˌkjuːpɪˈleɪʃən) n1. (Metallurgy) the process of recovering precious metals from lead by melting the alloy in a cupel and oxidizing the lead by means of an air blast2. (Metallurgy) the manufacture of lead oxide by melting and oxidizing lead
Translations
coppellazione

Cupellation

enUK

cupellation

[‚kyü·pə′lā·shən] (metallurgy) Method using a cupel for assaying precious metals. Process for refining gold and silver by alloying them with lead and then oxidizing the molten lead to separate the base metal from the precious metal.

Cupellation

 

oxidation melting of an alloy of lead with noble metals (gold and silver) to separate them in pure form. Cupellation is based on the fact that lead and other base metals are easily oxidized at high temperatures by atmospheric oxygen, whereas the noble metals are unchanged.

Cupellation is used in assaying to establish the purity of a sample (the content of the noble metals in their alloys). The process takes place in cupels, which are small cups made from a porous refractory material (bone ash, magnesite, and others), at a temperature of 850°-900°C. During cupellation, lead and other base metals are converted into molten oxides, which are absorbed by the cupel, whereas the noble metals remain on its surface as “beads.”

In metallurgy, cupellation is the operation of separating noble metals from argentiferous lead; it is carried out in reverberatory furnaces at a temperature of about 1000°C. Lead and base metals are oxidized by the oxygen blast. The mixture of oxides, in which lead oxide (PbO) predominates, is in liquid form and flows continuously from the surface of the melt into a receptacle. A gold-silver alloy that sometimes contains platinum metals is produced on the hearth of the furnace.

REFERENCES

Loskutov, F. M. Metallurgiia svintsa. Moscow, 1965.
Priborootbiranie i analiz blagorodnykh metallov. Edited by I. F. Barysh-nikov. Moscow, 1968.

V. L. BELOVA and IU. F. VAIMAN

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更新时间:2024/12/23 17:08:09