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单词 electrochemiluminescence
释义

Electrochemiluminescence


electrochemiluminescence

[i‚lek·trō‚kem·ē·ə‚lüm·ə′nes·əns] (physical chemistry) Emission of light produced by an electrochemical reaction. Also known as electrogenerated chemiluminescence.

Electrochemiluminescence

 

luminescence arising in the recombination of ion-radicals formed in the course of the electrolysis of a solution of an activator, such as isobenzofuran and isoindole, in an accompanying electrolyte, such as dimethyl formamide (seeLUMINESCENCE); the excited molecules of the activator formed as a result of the recombination of their ion-radicals are converted to the ground state, emitting light quanta. Electro-chemiluminescence may be used in indicator instruments: upon excitation of a luminophor by a changing electric field, the luminescence is concentrated near the electrode, and, by using electrodes with special shapes, flashing numbers and letters may be constructed. (See and CHEMILUMINES-CENCE.)

electrochemiluminescence


electrochemiluminescence

, electrochemoluminescence (ē-lek″trō-kēm″ĭ-loo″mĭ-nes′ĕns) (ē-lek″trō-kēm″ō-loo″mĭ-nes′ĕns) The production of visible light by an electrochemical reaction in which molecules, after becoming electronically excited, release visible electromagnetic energy when they return to their relaxed state. Electrochemiluminescence is used in laboratory science as a means of measuring the concentration of specific chemicals in solution. Light-emitting molecules that commonly bind to the chemical of interest are introduced into the solution, and the amount of light given off by the “labeled” or “tagged” chemical is measured.
AcronymsSeeECL
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更新时间:2024/12/24 4:03:47