The octahedra are connected by malonate anions, forming chains along the c-axis direction.
Tim de Klijn, Martin Lutz 2014, 'catena-Poly[[triaquamagnesium]-μ2-malonato]', Acta Crystallographica Section Ehttp://scripts.iucr.org/cgi-bin/paper?S1600536813034193. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Malonate or oxalate was found to be also essential in this degradation.
Xing Qin, Xianhua Sun, Huoqing Huang, Yingguo Bai, Yuan Wang, Huiying Luo, Bin Yao,Xiaoyu Zhang, Xiaoyun Su 2017, 'Oxidation of a non-phenolic lignin model compound by two Irpex lacteus manganese peroxidases:evidence for implication of carboxylate and radicals', Biotechnology for Biofuelshttp://link.springer.com/article/10.1186/s13068-017-0787-z. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The malonate group assumes an extended conformation.
S. Ranjith, K. Sakthi Murugesan, A. Subbiah Pandi, V. Dhayalan, A. K. Mohana Krishnan 2011, 'Diethyl 2-{[3-(2-methoxybenzyl)thiophen-2-yl]methylidene}malonate', Acta Crystallographica Section Ehttp://scripts.iucr.org/cgi-bin/paper?S1600536811022525. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
However, malonate has toxic effects that preclude its systemic administration in animals.
Laura Valls-Lacalle, Ignasi Barba, Elisabet Miró-Casas, Marisol Ruiz-Meana, AntonioRodríguez-Sinovas, David García-Dorado 2018, 'Selective Inhibition of Succinate Dehydrogenase in Reperfused Myocardium with IntracoronaryMalonate Reduces Infarct Size', Scientific Reportshttp://link.springer.com/article/10.1038/s41598-018-20866-4. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Malonate induced a neurological deficit associated with a striatal lesion.
Cindy Gueguen, Bruno Palmier, Michel Plotkine, Catherine Marchand-Leroux, ValérieC. Besson 2014, 'Neurological and Histological Consequences Induced by In Vivo Cerebral Oxidative Stress:Evidence for Beneficial Effects of SRT1720, a Sirtuin 1 Activator, and Sirtuin 1-MediatedNeuroprotective Effects of Poly(ADP-ribose) Polymerase Inhibition', PLoS ONE10.1371/journal.pone.0087367. Retrieved from PLOS CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Five contaminants were used in the study: methyl salicylate, parathion, diethyl malonate, phorate and potassium cyanide.
Nick Kassouf, Sara Syed, Joanne Larner, Richard Amlôt, Robert P Chilcott 2017, 'Evaluation of absorbent materials for use as ad hoc dry decontaminants during masscasualty incidents as part of the UK's Initial Operational Response (IOR).', PLoS ONEhttp://europepmc.org/articles/PMC5289487?pdf=render. Retrieved from PLOS CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The malonate ligands adopt two types of coordination mode, linking dysprosium centres to form a three-dimensional coordination polymer.
Mei Yang, Zhao-Feng Song, Rong-Hua Zeng, Zhan-Qiang Fang 2008, 'Poly[hexaaquatri-μ-malonato-didysprosium(III)]', Acta Crystallographica Section Ehttp://scripts.iucr.org/cgi-bin/paper?S1600536808015961. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
In this context, stoichiometric reactions of 1–9 with dimethyl malonate and di-iso-butyl malonate were carried out.
M. Tabassam, A. Farooq, M. Imran, S. R. Gillani, S. Saqib, Z. Mehmood, L. Mitu 2017, 'Reactivity of (η3-allyl)dicarbonylnitrosyl iron complexes with dimethyl malonate anddiisobutyl malonate', Bulletin of the Chemical Society of Ethiopiahttps://www.ajol.info/index.php/bcse/article/view/163109. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)