a radical chemical consisting of phosphorus and oxygen, represented by the symbol pO
Examples of 'phosphoryl' in a sentence
phosphoryl
The phosphoryl group adopts an anti orientation with respect to the carbonyl group.
Mehrdad Pourayoubi, Atekeh Tarahhomi, Arnold L. Rheingold, James A. Golen 2011, 'N,N′-Dicyclohexyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamide', Acta Crystallographica Section Ehttp://scripts.iucr.org/cgi-bin/paper?S1600536811043029. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Phosphoryl transfer reactions figure prominently in energy metabolism, signaling, transport and motility.
Jean C Summerton, Gregory M Martin, Jeffrey D Evanseck, Michael S Chapman 2014, 'Common hydrogen bond interactions in diverse phosphoryl transfer active sites.', PLoS ONEhttp://europepmc.org/articles/PMC4169622?pdf=render. Retrieved from PLOS CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The carbonyl and phosphoryl groups are in an antiperiplanar conformation.
Victor A. Trush, Kateryna E. Gubina, Yaroslav O. Gumeniuk, Tetyana Yu. Sliva, IrinaS. Konovalova 2012, 'Tetramethyl N,N′-(2,2,3,3,4,4-hexafluoro-1,5-dioxopentane-1,5-diyl)bis(phosphoramidate)',Acta Crystallographica Section Ehttp://scripts.iucr.org/cgi-bin/paper?S1600536812011191. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
It was prepared from nitroquinolinone, ethanol and phosphoryl chloride.
Daniel Limbach, Elena Stengelin, Dieter Schollmeyer, Heiner Detert 2016, '1-Ethyl-3-nitroquinolin-4(1H)-one', IUCrDatahttp://scripts.iucr.org/cgi-bin/paper?S2414314616001255. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Chitin benzoic acid esters were prepared using a phosphoryl mixed anhydride method.
Lok Ranjan Bhatt, Bo Mi Kim, Chai Ho Lee, Geu Beum Kwak, Kyu Yun Chai, Kim Hyun 2011, 'Preparation and Characterization of Chitin Benzoic Acid Esters', Moleculeshttp://www.mdpi.com/1420-3049/16/4/3029/. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The conformations of the carbonyl and phosphoryl groups are anti to each other.
Vladimir A. Ovchynnikov 2010, 'N-[Bis(benzylamino)phosphoryl]-2,2,2-trichloroacetamide', Acta Crystallographica Section Ehttp://scripts.iucr.org/cgi-bin/paper?S1600536810017873. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
For phosphoryl group transfer both binding partners need to form a tight complex.
Benjamin Scharein, Georg Groth 2011, 'Phosphorylation alters the interaction of the Arabidopsis phosphotransfer proteinAHP1 with its sensor kinase ETR1.', PLoS ONEhttp://europepmc.org/articles/PMC3166298?pdf=render. Retrieved from PLOS CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Absorption of a photon inhibits the cyclase activity, most likely by inhibiting the phosphoryl transfer.
Yuehui Tian, Shiqiang Gao, Eva Laura von der Heyde, Armin Hallmann, Georg Nagel 2018, 'Two-component cyclase opsins of green algae are ATP-dependent and light-inhibitedguanylyl cyclases', BMC Biologyhttp://link.springer.com/article/10.1186/s12915-018-0613-5. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Organophosphates are organic substances that contain a phosphoryl or a thiophosphoryl bond.
Paola Carullo, Giovanni Paolo Cetrangolo, Luigi Mandrich, Giuseppe Manco, FerdinandoFebbraio 2015, 'Fluorescence Spectroscopy Approaches for the Development of a Real-Time OrganophosphateDetection System Using an Enzymatic Sensor', Sensorshttp://www.mdpi.com/1424-8220/15/2/3932. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The viability of living systems depends inextricably on enzymes that catalyze phosphoryl transfer reactions.
James L Hougland, Alexander V Kravchuk, Daniel Herschlag, Joseph A Piccirilli 2005, 'Functional identification of catalytic metal ion binding sites within RNA.', PLoS Biologyhttp://europepmc.org/articles/PMC1184590?pdf=render. Retrieved from PLOS CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)