Standard reaction conditions for the desilylation of acetylated furanoside (riboside,arabinoside and xyloside) derivatives facilitate acyl migration.
O. P. Chevallier, M. E. Migaud 2006, 'Investigation of acetyl migrations in furanosides', Beilstein Journal of Organic Chemistryhttps://doi.org/10.1186/1860-5397-2-14. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The studies on the recently discovered pyranoside-into-furanoside rearrangement have led us to conformational investigations of furanosides upon their total sulfation.
Alexey G. Gerbst, Vadim B. Krylov, Dmitry A. Argunov, Maksim I. Petruk, Arsenii S.Solovev, Andrey S. Dmitrenok, Nikolay E. Nifantiev 2019, 'Influence of per-O-sulfation upon the conformational behaviour of common furanosides',Beilstein Journal of Organic Chemistryhttps://doi.org/10.3762/bjoc.15.63. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)