of, pertaining to, or characteristic of the allyl group
Word origin
[1855–60; allyl + -ic]This word is first recorded in the period 1855–60. Other words that entered Englishat around the same time include: barrage, keyword, lavabo, specialist, superheat-ic is a suffix forming adjectives from other parts of speech, occurring originally inGreek and Latin loanwords (metallic; poetic; archaic; public) and, on this model, used as an adjective-forming suffix with the particular senses“having some characteristics of” (opposed to the simple attributive use of the basenoun) (balletic; sophomoric); “in the style of” (Byronic; Miltonic); “pertaining to a family of peoples or languages” (Finnic; Semitic; Turkic)
Examples of 'allylic' in a sentence
allylic
Copper-catalyzed allylic desymmetrizations are, so far, limited to carbocyclic products with two tertiary stereocenters.
Reece Jacques, Robert D. C. Pullin, Stephen P. Fletcher 2019, 'Desymmetrization of meso-bisphosphates using copper catalysis and alkylzirconocenenucleophiles', Nature Communicationshttp://link.springer.com/article/10.1038/s41467-018-07871-x. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
The possible mechanisms of formation of the allylic oxidation products were proposed.
Agnieszka Wróblewska 2014, 'The Epoxidation of Limonene over the TS-1 and Ti-SBA-15 Catalysts', Moleculeshttp://www.mdpi.com/1420-3049/19/12/19907. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Possible mechanisms for their formation via allylic radical intermediates are discussed.
Dobson, Gary, Christie, William W., Sébédio, Jean Louis 1996, 'The nature of cyclic fatty acids formed in heated vegetable oils', Grasas y Aceiteshttp://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/839/848. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Branched, cyclic, allylic and benzylic alkylamino/arylamino groups were introduced into the quinone moiety.
Jeremić Marko, Dinić Jelena, Pešić Milica, Stepanović Marija, Novaković Irena, ŠeganDejan, Sladić Dušan 2018, 'Alkylamino and aralkylamino derivatives of avarone and its mimetic as selective agentsagainst non-small cell lung cancer cells, their antibacterial and antifungal potential',Journal of the Serbian Chemical Societyhttp://www.doiserbia.nb.rs/img/doi/0352-5139/2018/0352-51391800062J.pdf. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Microbial transformations afforded hydroxylactones with the hydroxy group in the allylic position.
Czesław Wawrzeńczyk, Aleksandra Grudniewska 2013, 'Lactones 41. Synthesis and Microbial Hydroxylation of Unsaturated Terpenoid Lactoneswith p-Menthane Ring Systems', Moleculeshttp://www.mdpi.com/1420-3049/18/3/2778. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Regioselectivity was high when some substituted cyclic allylic bromides were investigated.
Suzanne M. Perala, Brian P. Conrad, Christine A. Hughey, John H. Shugart, Gary W.Breton 2001, 'Use of Cyclic Allylic Bromides in the Zinc–Mediated Aqueous Barbier–GrignardReaction', Moleculeshttp://www.mdpi.com/1420-3049/6/8/655/. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Allylic alcohols are valuable precursors in the synthesis of pharmaceutical intermediates, agrochemicals and natural products.
Anna M. Bogazkaya, Clemens J. von Bühler, Sebastian Kriening, Alexandrine Busch, AlexanderSeifert, Jürgen Pleiss, Sabine Laschat, Vlada B. Urlacher 2014, 'Selective allylic hydroxylation of acyclic terpenoids by CYP154E1 from Thermobifidafusca YX', Beilstein Journal of Organic Chemistryhttps://doi.org/10.3762/bjoc.10.137. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Difunctional allylic terpenes are important synthetic building blocks.
Paz J. Luis, Rodrigues J. Augusto R. 2003, 'Preparation of aromatic geraniol analogues via a Cu(I)-mediated Grignard coupling',Journal of the Brazilian Chemical Societyhttp://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000600014. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
It was transformed to potential allylic and chiral intermediates.
Jacqueline Kautz, Willian Feltrin, Eric S. Sales, Vera Lucia Eifler-Lima, Aloir A.Merlo 2015, 'REAÇÃO DE CONDENSAÇÃO DO GLICEROL COM COMPOSTOS CARBONÍLICOS. SÍNTESE, CARACTERIZAÇÃOE APLICAÇÃO EM CRISTAIS LÍQUIDOS', Química Novahttp://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422015000801053&lng=en&tlng=en. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)
Various types of alkynes and allylic silanes were applicable to the present allylindation.
Yoshihiro Nishimoto, Junyi Yi, Tatsuaki Takata, Akio Baba, Makoto Yasuda 2018, 'Regio- and Stereoselective Allylindation of Alkynes Using InBr3 and Allylic Silanes:Synthesis, Characterization, and Application of 1,4-Dienylindiums toward Skipped Dienes',Moleculeshttp://www.mdpi.com/1420-3049/23/8/1884. Retrieved from DOAJ CC BY 4.0 (https://creativecommons.org/licenses/by-sa/4.0/legalcode)