单词 | trithiocarbonic acid |
释义 | > as lemmastri-thiocarbonic acid Categories » thiocarbonic adj. Brit. , U.S. in thiocarbonic acid: in derivatives, as mono-thiocarbonic acid, di-thiocarbonic acid, tri-thiocarbonic acid: the last, H2CS3, is a dark yellow strongly smelling oil, very easily decomposed by heating into CS2 and H2S; esters of dithiocarbonic acid, H2COS2, and of monothiocarbonic acid, H2CO2S, are known.trithiocarbonic acid Prefix denoting that three atoms of sulphur have been substituted for three atoms of oxygen in the substance designated by the rest of the name; e.g. trithiocarbonic acid, H2CS3, derived from carbonic acid, H2CO3; trithiocarbonate, a salt of this acid. In many cases, however, tri- refers to the whole substance and not to the sulphur alone; e.g. trithio-acetaldehyde, (CH3CHS)3, a compound of three molecules of thio-acetaldehyde, CH3CHS. ΚΠ 1894 H. F. Morley & M. M. P. Muir Watts' Dict. Chem. (rev. ed.) IV. 692 Tri-Thio-Citric Ether C3H5O(CO.SEt)3..Oil, smelling like mercaptan. 1899 E. F. Smith tr. V. von Richter Org. Chem. (ed. 3) I. 203 Trithio-formaldehyde (CH2S)3, melts at 216°. 1910 A. J. Walker & O. E. Mott tr. A. F. Holleman Text-bk. Org. Chem. (ed. 3) 348 Carbon disulphide..With alkali-metal or alkaline-earth-metal sulphides it yields trithiocarbonates. < as lemmas |
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