单词 | stereoelectronic |
释义 | > as lemmasstereoelectronic stereoelectronic adj. Brit. /ˌstɛrɪəʊᵻlɛkˈtrɒnɪk/ , /ˌstɛrɪəʊˌɛlɛkˈtrɒnɪk/ , /ˌstɪərɪəʊᵻlɛkˈtrɒnɪk/ , /ˌstɪərɪəʊˌɛlɛkˈtrɒnɪk/ , U.S. /ˌstɛrioʊəˌlɛkˈtrɑnɪk/ , /ˌstɛrioʊiˌlɛkˈtrɑnɪk/ , /ˌstɪrioʊəˌlɛkˈtrɑnɪk/ , /ˌstɪrioʊiˌlɛkˈtrɑnɪk/ Chemistry pertaining to the relative positions of the electron orbitals in reacting molecules.ΘΚΠ the world > matter > chemistry > atomic chemistry > [adjective] > relating to orbitals hybrid1939 trigonal1939 stereoelectronic1956 streamer1966 1956 Jrnl. Amer. Chem. Soc. 78 6273/1 The tendency of bromine to adopt the axial orientation in the bromination of an enol would seem to indicate that stereoelectronic control is unusually large in this case since the opposing steric effect is certainly quite large. 1972 Jrnl. Amer. Chem. Soc. 94 3657/1 It is expected that σ-π conjugation would have similar stereoelectronic requirements to p-π conjugation. < as lemmas |
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