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单词 stereoelectronic
释义

> as lemmas

stereoelectronic
stereoelectronic adj.
Brit. /ˌstɛrɪəʊᵻlɛkˈtrɒnɪk/
,
/ˌstɛrɪəʊˌɛlɛkˈtrɒnɪk/
,
/ˌstɪərɪəʊᵻlɛkˈtrɒnɪk/
,
/ˌstɪərɪəʊˌɛlɛkˈtrɒnɪk/
,
U.S. /ˌstɛrioʊəˌlɛkˈtrɑnɪk/
,
/ˌstɛrioʊiˌlɛkˈtrɑnɪk/
,
/ˌstɪrioʊəˌlɛkˈtrɑnɪk/
,
/ˌstɪrioʊiˌlɛkˈtrɑnɪk/
Chemistry pertaining to the relative positions of the electron orbitals in reacting molecules.
ΘΚΠ
the world > matter > chemistry > atomic chemistry > [adjective] > relating to orbitals
hybrid1939
trigonal1939
stereoelectronic1956
streamer1966
1956 Jrnl. Amer. Chem. Soc. 78 6273/1 The tendency of bromine to adopt the axial orientation in the bromination of an enol would seem to indicate that stereoelectronic control is unusually large in this case since the opposing steric effect is certainly quite large.
1972 Jrnl. Amer. Chem. Soc. 94 3657/1 It is expected that σ-π conjugation would have similar stereoelectronic requirements to p-π conjugation.
extracted from stereo-comb. form
<
as lemmas
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