单词 | sorbitan |
释义 | sorbitann. Chemistry. Any of a number of cyclic ethers which are monoanhydrides of sorbitol; spec. the 1,4-anhydride, CH2OH·CHOH·CH·(CHOH)2·CH2O, a colourless crystalline solid. Frequently attributive in names of fatty-acid esters of these compounds, which are used as emulsifiers and surfactants. ΘΚΠ the world > matter > chemistry > organic chemistry > ether > [noun] > named > others tartaric ether1789 margaric ether1848 phenetole1851 tellurethyl1852 tributyrin1855 oxamic ether1857 phenomethole1857 meconic ether1865 saccharic ether1868 iodhydrin1872 saccharide1881 ethoxyethane1894 sorbitan1938 styrene oxide1939 nonoxynol1967 1938 Industr. & Engin. Chem. Nov. 1222/2 The inner ether hypothesis was further tested by substituting a mixture of preformed sorbitol inner ethers, or sorbitans, for the sorbitol. 1950 R. E. Kirk & D. F. Othmer Encycl. Chem. Technol. V. 688 Anhydrides of certain hexahydric alcohols and their derivatives, as sorbitan and polyoxyethylene sorbitan esters of fatty acids, are used as emulsifiers and also possess emollient properties. 1958 Martindale's Extra Pharmacopœia (ed. 24) 696 The ether-esters, such as sorbitan oleate, are active water-in-oil emulsifying agents, while the polyoxyethylene derivatives mostly produce oil-in-water emulsions. 1969 tr. Schönfeldt's Surface Active Ethylene Oxide Adducts iv. 607 A composition containing glycine, phosphoric acid, and, e.g...ethoxylated sorbitan monolaurate as adduct, or sorbitan mono-oleate, is recommended as an antioxidant for fats. 1976 Nature 26 Aug. 777/2 By use of surfactants such as sorbitan stearates, water can be emulsified in hydrocarbon solvents and then readily supercooled. This entry has not yet been fully updated (first published 1986; most recently modified version published online September 2018). < n.1938 |
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