单词 | schiff |
释义 | Schiffn. Chemistry. Used attributively and in the possessive to designate things Schiff devised or investigated. a. Schiff base n. (also Schiff's base) any organic compound having the structure R1R2CNR3. ΘΚΠ the world > matter > chemistry > organic chemistry > organic bases > [noun] creatine1835 cystine1843 ammeline1846 creatinine1847 thialdine1847 toluidine1850 pyrrole base1853 parapicoline1857 pinacoline1866 xanthinine1868 choline1869 xanthocreatinine1887 xanthocreatine1891 Schiff base1892 tar base1921 thiocholine1929 1892 Jrnl. Chem. Soc. 62 ii. 1189 Schiff's bases, derived from aromatic aldehydes, have a similar constitution to benzylidenaniline, PhN:CHPh, which serves as the type of these compounds. 1915 P. E. Spielmann tr. V. von Richter Org. Chem. 383 Hydrocyanic acid attaches itself similarly to the oximes..and to the Schiff bases. 1951 I. L. Finar Org. Chem. I. xiii. 257 Primary amines combine with aromatic aldehydes to form Schiff bases. 1971 Nomencl. Org. Chem. (I.U.P.A.C.) (ed. 2) 258 Compounds R1R2CNR3 have the class name ‘azomethines’. When the nitrogen atom is substituted, this class of compound has the generic name ‘Schiff's bases’. 1975 Nature 30 Oct. 823/2 In visual pigments, retinal is bound by way of a Schiff base linkage to the protein. b. Schiff reaction n. (also Schiff's reaction) the action of aldehydes of restoring the magenta colour to Schiff's reagent. ΘΚΠ the world > matter > chemistry > organic chemistry > organic chemical tests > [noun] > Schiff's test Schiff reaction1894 Schiff test1902 1894 W. H. Perkin & F. S. Kipping Org. Chem. i. viii. 122 Aldehyde may be detected..by the ‘magenta’ or ‘rosaniline test’ (Schiff's reaction). 1897 Chem. News 9 July 23/2 (heading) Schiff reaction applied to acid fuchsine. 1951 I. L. Finar Org. Chem. I. viii. 123 Ketones do not give Schiff's reaction. c. Schiff reagent n. (also Schiff's reagent) an acid solution of fuchsin (magenta, rosaniline) decolorized by sulphur dioxide or potassium metabisulphite. ΘΚΠ the world > matter > chemistry > chemical tests > [noun] > reagents > other Millon's reagent1872 orcinol1880 rubeanic acid1891 tetrazolium1895 Schiff reagent1897 Tollens'(s) reagent1904 1897 Jrnl. Chem. Soc. 72 ii. 468 The author [sc. B. von Bittó] has also studied the behaviour of Schiff's reagent (a 0·025 per cent. solution of magenta decolorised by passing sulphurous anhydride through it)..with a number of aldehydes and ketones. 1929 Evers & Elsdon Analysis of Drugs & Chemicals 279 The proportion of formaldehyde may be determined by the use of Schiff's reagent. 1964 M. Hynes Med. Bacteriol. (ed. 8) xxvii. 412 Schiff reagent. d. Schiff test n. (also Schiff's test) the Schiff reaction employed as a test for aldehydes. ΘΚΠ the world > matter > chemistry > organic chemistry > organic chemical tests > [noun] > Schiff's test Schiff reaction1894 Schiff test1902 1902 J. B. Cohen Theoret. Org. Chem. ix. 128 A further reaction for aldehydes is known as Schiff's test. 1949 English & Cassidy Princ. Org. Chem. xi. 202 Advantage is taken of the greater reactivity of aldehydes toward bisulfite in the Schiff test for aldehydes. 1972 R. O. C. Norman & D. J. Waddington Mod. Org. Chem. xii. 174 The addition of an aldehyde to this colourless solution restores the pink colour of the dye (Schiff's test). This entry has not yet been fully updated (first published 1982; most recently modified version published online June 2019). < |
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