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单词 pyrophosphate
释义

pyrophosphaten.

Brit. /ˌpʌɪrə(ʊ)ˈfɒsfeɪt/, U.S. /ˌpaɪroʊˈfɑsˌfeɪt/
Origin: Formed within English, by compounding. Etymons: pyro- comb. form, phosphate n.
Etymology: < pyro- comb. form + phosphate n. (see quot. 1827).
Chemistry.
A salt or ester, or the anion, of pyrophosphoric acid; a group or linkage formed from two condensed phosphate groups.
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the world > matter > chemistry > chemical substances > esters > [noun] > salts, esters, or anions > others
citrate1788
pyrophosphate1827
paraphosphate1837
thioglycolate1877
isatogenate1882
orotate1905
hydrazoate1910
octoate1911
octanoate1945
1827 T. Clark in Edinb. Jrnl. Sci. 7 301 By simply drying the common phosphate of soda and heating it to redness, an entirely new salt had been produced. This new salt I shall, in the sequel of this paper, call pyrophosphate of soda.
1849 Q. Jrnl. Chem. Soc. 1 183 In the year 1834, Persoz..proposed the use of pyrophosphate of ammonia as a means of separating the oxide of nickel from oxide of cobalt.
1912 E. Feilmann tr. E. Molinari Treat. Inorg. Chem. 348 The pyrophosphates..give a precipitate with copper salts, which is soluble in excess of pyrophosphate.
1950 N. V. Sidgwick Chem. Elements I. 746 Ethyl pyrophosphate Et4P2O7 can be made from the silver salt and ethyl iodide.
1957 G. E. Hutchinson Treat. Limnol. I. xii. 728 Though pyrophosphate plays an important role inside the organism, it is easily hydrolyzed and only orthophosphate is likely to be of importance in the environment.
1970 E. J. Ambrose & D. M. Easty Cell Biol. vii. 248 There is another type of reaction..in which a sugar phosphate reacts with another sugar to form a disaccharide and inorganic pyrophosphate.
This entry has been updated (OED Third Edition, December 2007; most recently modified version published online March 2022).
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n.1827
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