单词 | pseudo-base |
释义 | pseudo-basen. Chemistry. A compound which is not itself a base but which exists in equilibrium with, or is easily converted into, a basic form and thus undergoes some typical reactions of bases. ΘΚΠ the world > matter > chemistry > chemical substances > bases > [noun] > pseudo-base pseudo-base1899 1899 Jrnl. Chem. Soc. 76 i. 400 Pseudo-bases are substances which, by isomeric change, are capable of giving a true base of the ammonium hydroxide type from which the salts are derived. 1951 C. R. Noller Chem. Org. Compounds xxx. 591 The N-alkyl-α-pyridones are obtained by the oxidation of the quaternary hydroxides. These strong bases appear to be in equilibrium with the α-hydroxydihydropyridines, which are called pseudo bases. 1960 K. W. Bentley Natural Pigments i. 14 The α- and γ-pyranols are, in fact, pseudo bases, forming a salt and water on treatment with acid. 1990 Amer. Jrnl. Bot. 77 453/1 Differences in anthocycanin production and colorless anthocycanin pseudo-base synthesis between terrestrial and aquatic plants. Derivatives pseudo-ˈbasic adj. ΘΚΠ the world > matter > chemistry > chemical substances > bases > [adjective] > pseudo-basic pseudo-basic1906 1906 Jrnl. Amer. Chem. Soc. 28 911 The pseudoacid pseudobasic nature of the proteins is considered to be a matter of such importance that it is extensively discussed. 1921 Jrnl. Chem. Soc. 119 1470 One of the more characteristic reactions of pseudo-basic carbinols is the formation of ethers by simple treatment with alcohols. 1978 Jrnl. Physical Chem. 82 653/2 The appearance of the radical cation in aqueous solution is conjugated with the presence of the OH adduct via the pseudobasic equilibria A, B, and C. ˌpseudo-baˈsicity n. ΘΚΠ the world > matter > chemistry > chemical substances > bases > [noun] > pseudo-base > quality of being pseudo-basic pseudo-basicity1927 1927 Ann. Rep. Progr. Chem. 24 115 The hydroxide ion tends to co-ordinate with positive carbon, whereas very stable anions like chloride..tend to retain their ionic condition..: thus arises the phenomenon of pseudo-basicity. 1967 Jrnl. Amer. Chem. Soc. 89 66/1 The addition of a third benzene ring gives a further increase in pseudo-basicity. This entry has been updated (OED Third Edition, September 2007; most recently modified version published online March 2022). < |
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