oximen.

Brit.

/ˈɒksiːm/, U.S.

/ˈɑkˌsim/

Forms: 1800s– oxim, 1800s– oxime.

Origin: A borrowing from German. Etymon: German Oxim.

Etymology: < German Oxim (V. Meyer & A. Janny 1882, in Berichte der Deutsch. Chem. Ges. 15 1324) < oxy- oxy- comb. form² + im- (in Imid imide n.). Compare in the same source German Oximid oximide n.The imides contain the radical NH, the oximes N(OH). N.E.D. (1904) gives the pronunciation for the form oxime as (ǫ·ksəim) /ˈɒksaɪm/, and that for the form oxim as (ǫ·ksim) /ˈɒksɪm/.

Chemistry.

Any organic compound containing the group N(OH) attached to a carbon atom, formed by the reaction of hydroxylamine with an aldehyde or ketone. Cf. aldoxime n. at aldo- comb. form 2, ketoxime n. at keto- comb. form 1a.

ΘΚΠ

the world > matter > chemistry > organic chemistry > organic compounds > [noun] > by constituent molecules

acetylide1863

oxime1883

osone1889

oximide1893

organoalkali1932

ylid1951

phenolic1956

organo-borane1957

plastoquinone1958

nitrene1960

tetrahedrane1964

1883 Science 4 May 366/2 E. Nägeli obtained from mesityloxide, mesityloxime (C₆H₁₀=NOH).

1889 Jrnl. Amer. Chem. Soc. 11 110 An intimate research into the oxims of benzil.

1906 H. F. Morley & M. M. P. Muir Watts' Dict. Chem. III. 660/2 Oxims are split up by boiling HClAq into hydroxylamine and the original aldehyde or ketonic compound.

1938 C. F. H. Allen & A. H. Blatt in H. Gilman Org. Chem. I. vi. 569 Oximes, hydrazones, and phenylhydrazones are utilized primarily for isolating and identifying carbonyl compounds.

1958 Science 31 Jan. 222/3 When this solution is bleached with orange light, the retinene reacts rapidly with hydroxylamine to form all-trans retinene oxime.

1985 P. J. Wingate Before Bridge xx. 204 I even hinted that the oxime of dehydropyrethrosin..might some day cure cancer or the common cold.

This entry has been updated (OED Third Edition, March 2005; most recently modified version published online March 2022).

单词	oxime
释义	oximen. Brit. /ˈɒksiːm/, U.S. /ˈɑkˌsim/ Forms: 1800s– oxim, 1800s– oxime. Origin: A borrowing from German. Etymon: German Oxim. Etymology: < German Oxim (V. Meyer & A. Janny 1882, in Berichte der Deutsch. Chem. Ges. 15 1324) < oxy- oxy- comb. form² + im- (in Imid imide n.). Compare in the same source German Oximid oximide n.The imides contain the radical NH, the oximes N(OH). N.E.D. (1904) gives the pronunciation for the form oxime as (ǫ·ksəim) /ˈɒksaɪm/, and that for the form oxim as (ǫ·ksim) /ˈɒksɪm/. Chemistry. Any organic compound containing the group N(OH) attached to a carbon atom, formed by the reaction of hydroxylamine with an aldehyde or ketone. Cf. aldoxime n. at aldo- comb. form 2, ketoxime n. at keto- comb. form 1a. ΘΚΠ the world > matter > chemistry > organic chemistry > organic compounds > [noun] > by constituent molecules acetylide1863 oxime1883 osone1889 oximide1893 organoalkali1932 ylid1951 phenolic1956 organo-borane1957 plastoquinone1958 nitrene1960 tetrahedrane1964 1883 Science 4 May 366/2 E. Nägeli obtained from mesityloxide, mesityloxime (C₆H₁₀=NOH). 1889 Jrnl. Amer. Chem. Soc. 11 110 An intimate research into the oxims of benzil. 1906 H. F. Morley & M. M. P. Muir Watts' Dict. Chem. III. 660/2 Oxims are split up by boiling HClAq into hydroxylamine and the original aldehyde or ketonic compound. 1938 C. F. H. Allen & A. H. Blatt in H. Gilman Org. Chem. I. vi. 569 Oximes, hydrazones, and phenylhydrazones are utilized primarily for isolating and identifying carbonyl compounds. 1958 Science 31 Jan. 222/3 When this solution is bleached with orange light, the retinene reacts rapidly with hydroxylamine to form all-trans retinene oxime. 1985 P. J. Wingate Before Bridge xx. 204 I even hinted that the oxime of dehydropyrethrosin..might some day cure cancer or the common cold. This entry has been updated (OED Third Edition, March 2005; most recently modified version published online March 2022). < n.1883
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