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单词 oleoyl
释义

oleoyln.

Brit. /ˈəʊlɪˌəʊɪl/, U.S. /oʊˈliəl/
Forms: 1900s– oleoyl, 1900s– oleyl.
Origin: Formed within English, by derivation. Etymons: oleic acid n. at oleic adj. 1, -oyl suffix.
Etymology: < ole- (in oleic acid n. at oleic adj. 1) + -oyl suffix. Compare oleo- comb. form.With the earlier form oleyl compare -yl suffix; the current form oleoyl is perhaps influenced by oleo- comb. form. O.E.D. Suppl. (1982) enters this under oleyl and gives the pronunciation as (ōu·lĭˌil, -əil) /ˈəʊlɪɪl/, /ˈəʊlɪaɪl/.
Chemistry.
The hydrocarbon radical —CH3(CH2)7CH=CH(CH2)7CH2, derived from oleic acid; cis-9-octadecen-1-oyl. Usually attributive.Recorded earliest in oleoyl alcohol n. at Compounds.
ΘΚΠ
the world > matter > chemistry > organic chemistry > hydrocarbons > [noun] > hydrocarbon radicals > others
mesityl1838
carbyl1840
melissyl1852
neopentyl1876
oleoyl1903
1903 Jrnl. Chem. Soc. 84 i. 730 Ethyl oleate gave oleyl alcohol, C18H36O, as a colourless liquid.
1936 Proc. Royal Soc. A. 155 688 The double bond of the oleyl group is being removed from the water surface.
1951 R. E. Kirk & D. F. Othmer Encycl. Chem. Technol. VI. 271 The reaction of acetylene with oleyl alcohol gives vinyl oleyl ether, which is polymerizable and copolymerizable with other vinyl monomers.
1965 Nomencl. Org. Chem. (I.U.P.A.C.) C. 112 (table) Names of acids... Oleic. Acyl radicals... Oleoyl.
1970 R. W. McGilvery Biochemistry xvi. 334 The predominant residue in human adipose tissue is the singly unsaturated oleoyl group.
2002 Bioconjugate Chem. 13 378 Transfection efficiency was also greatly reduced when a ‘disorder’-inducing chain like an oleyl (cis-9-octadecenyl) segment was added to these cholesteryl amphiphiles.

Compounds

oleoyl alcohol n. an oily liquid alcohol, C18H35OH, which occurs in fish oils and is used in the manufacture of surface-active agents; cis-9-octadecen-1-ol.
ΘΚΠ
the world > matter > chemistry > organic chemistry > alcohols > [noun] > other named alcohols
melissin1848
melissic alcohol1852
toluylic alcohol1857
melissylic alcohol1862
citronellol1872
pararosaniline1879
oenanthic alcohol1880
arabitol1887
hydrol1897
thiol1900
nerol1903
oleoyl alcohol1903
pyruvic alcohol1909
oenanthotoxin1911
hexadecanol1914
lauryl alcohol1915
batyl alcohol1922
chimyl alcohol1924
1903*Oleyl alcohol [see main sense].
1972 Materials & Technol. V. ix. 262 Oleyl alcohol can be epoxidised with peracids to yield polyhydroxy compounds.
1995 Biochemistry 310 389 Oleoyl alcohol ((Z)-9-octadecen-1-ol) and methyl oleate were unable to displace FadL-specific binding of (3H)oleate.
This entry has been updated (OED Third Edition, March 2004; most recently modified version published online March 2022).
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n.1903
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