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单词 nitroaniline
释义

nitroanilinen.

Brit. /ˌnʌɪtrəʊˈanᵻliːn/, /ˌnʌɪtrəʊˈanl̩iːn/, /ˌnʌɪtrəʊˈanᵻlɪn/, /ˌnʌɪtrəʊˈanl̩ɪn/, U.S. /ˌnaɪtroʊˈænəl(ə)n/
Forms: 1800s nitro-anilin, 1800s– nitraniline Brit. /ˌnʌɪˈtranᵻliːn/, /ˌnʌɪˈtranl̩iːn/, /ˌnʌɪˈtranᵻlɪn/, /ˌnʌɪˈtranl̩ɪn/, U.S. /ˌnaɪˈtrænələn/, 1800s– nitroaniline.
Origin: Formed within English, by compounding; perhaps modelled on a German lexical item. Etymons: nitro- comb. form, aniline n.
Etymology: < nitro- comb. form + aniline n., perhaps after German Nitranilin (1845, by the authors of quot. 1848, in Ann. der Chem. u. Pharm. 54 27; this is the German version of the paper read in London in April 1845 but not published in English until the following year). N.E.D. (1907) enters this under nitraniline and gives the pronunciation as (nəitræ·niləin) /naɪˈtrænɪlaɪn/.
Chemistry.
Each of three isomeric yellow or orange crystalline compounds, C6H4(NO2)(NH2), which are derivatives of aniline having a nitro group attached to the carbon ring, and are used in the manufacture of dyes; nitrophenylamine. N-nitroaniline n. a pearly-white crystalline compound, NO2NHC6H5, isomeric with nitroaniline, but with the nitro group attached to the amine group; phenylnitramine.
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the world > matter > chemistry > crystallography (general) > crystal (general) > [noun] > crystalline compound > specific
alcoholate1816
alcoate1828
absinthin1834
nitroaniline1848
nitroanisidine1850
purpurein1864
quinizarin1873
phenazoxine1887
phenanthridine1890
1848 J. S. Muspratt & A. W. Hofmann in Mem. & Proc. Chem. Soc. London 1845–8 3 111 (title) On nitraniline, a new product of decomposition of dinitrobenzol.
1897 T. C. Allbutt et al. Syst. Med. II. 952 The presence of aniline, nitro-aniline or some coloured product due to the reduction of the nitro-benzole.
1955 B. C. L. Kemp Elem. Org. Chem. (new ed.) xix. 264 Meta-nitraniline is usually prepared by partial reduction of meta-dinitrobenzene, using ammonium sulphide as reducing agent.
1967 I. L. Finar Org. Chem. (ed. 5) I. xxiii. 623 Hughes et al. (1956) have studied the rearrangement of N-nitroaniline in sulphuric acid.
1985 H. Maskell Physical Basis Org. Chem. v. 173 We may read that the pK of p-nitroaniline is 0.99 when the author means that the pKAH of the conjugate acid..is 0.99.
This entry has been updated (OED Third Edition, December 2003; most recently modified version published online March 2022).
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n.1848
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