单词 | metallocene |
释义 | > as lemmasmetallocene metallocene n. Brit. /mᵻˈtalə(ʊ)siːn/ , U.S. /məˈtæləˌsin/ Chemistry any of a group of organometallic compounds that consist of a metal atom bonded between two cyclopentadienyl (or similar aromatic) rings in a sandwich structure, used esp. as catalysts in polymer synthesis; cf. ferrocene n.ΚΠ 1959 Jrnl. Amer. Chem. Soc. 81 3484/2 Another interesting feature of the relative rates recorded in Table I is the order of effectiveness of metallocene derivatives of Group VIII metals in stabilizing adjacent carbonium ion centers; ferrocene < ruthenocene < osmocene. 1994 M. Bochmann Organometallics II. iv. 53 The presence of ligands other than cyclopentadienyl in a metallocene complex enforces a geometry in which the Cp ligands are no longer co-planar; they adopt a ‘bent sandwich’ structure. < as lemmas |
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