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单词 manganese dioxide
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manganese dioxide
manganese dioxide n. manganese( iv) oxide, a grey-black solid, MnO2, which occurs naturally as pyrolusite and is used as a catalyst, oxidizing agent, depolarizer in dry cells, and pigment.
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the world > the earth > minerals > types of mineral > oxides and hydroxides > [noun] > rutile and uranite groups A02 > manganese dioxide
brownstone1657
manganese1662
magnesia1677
soap of glass1815
pyrolusite1828
varvicite1829
polianite1849
manganese dioxide1866
pelagite1876
manganese oxide1882
1866 H. E. Roscoe Lessons Elem. Chem. xxi. 190 Manganese Dioxide, MnO2, is the common black ore of manganese, and is termed pyrolusite by mineralogists; it can be artificially formed by adding a solution of bleaching powder to a manganous salt.
1946 Nature 3 Aug. 155/2 Manganese dioxide is reduced with great ease to form divalent manganese ion by sulphydryl compounds.
1988 F. A. Cotton & G. Wilkinson Adv. Inorg. Chem. (ed. 5) xviii. 706 Manganese dioxide is inert to most acids except when heated, but it does not dissolve to give MnIV in solution; instead it functions as an oxidizing agent.
1998 Tetrahedron Lett. 39 3815 Propargylic and benzylic alcohols can be oxidized with activated manganese dioxide in the presence of stabilized Wittig reagents to generate alpha, beta-unsaturated esters directly.
extracted from manganesen.
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