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单词 isoquinoline
释义

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isoquinoline
isoquinoline n.
Brit. /ˌʌɪsə(ʊ)ˈkwɪnəliːn/
,
/ˌʌɪsə(ʊ)ˈkwɪnl̩iːn/
,
/ˌʌɪsə(ʊ)ˈkwɪnəlɪn/
,
/ˌʌɪsə(ʊ)ˈkwɪnl̩ɪn/
,
U.S. /ˌaɪsoʊˈkwɪnələn/
[ < French isoquinoléine (Hoogewerff & Van Dorp 1885, in Rec. des Trav. chim. des Pays-Bas IV. 128)] a low-melting, crystalline, bicyclic compound, C9H7N, found in coal tar and forming the nucleus of many alkaloids.
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the world > matter > chemistry > organic chemistry > chemicals from tar > [noun]
naphthalene1821
idryl1845
picoline1846
fluorene1867
fluoranthene1878
isoquinoline1886
indene1888
1886 Jrnl. Chem. Soc. 50 78 By adding concentrated sulphuric acid to an alcoholic solution of crude quinoline from coal-tar, the sulphates of quinoline and isoquinoline, C9H7N, are precipitated.
1932 I. D. Garrard Introd. Org. Chem. xii. 180 Morphine is one of the alkaloids obtained from opium. It is a derivative of isoquinoline.
1960 R. M. Acheson Introd. Chem. Heterocyclic Compounds vi. 231 Many alkaloids (e.g. papaverine) contain either the aromatic, or the reduced, isoquinoline system.
1972 N. L. Allinger et al. Org. Chem. xxviii. 746 Isoquinoline may be synthesized from benzaldehyde by a cyclization reaction known as the Pomeranz–Fritsch synthesis.
extracted from iso-comb. form
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