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单词 isopropylidene
释义

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isopropylidene
isopropylidene n.
Brit. /ˌʌɪsə(ʊ)prəʊˈpʌɪlᵻdiːn/
,
/ˌʌɪsə(ʊ)prəʊˈpɪlᵻdiːn/
,
U.S. /ˌaɪsoʊˌproʊˈpɪlᵻˌdin/
the bivalent radical (CH3)2C=, frequently introduced into compounds by reaction with acetone.
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the world > matter > chemistry > organic chemistry > hydrocarbons > [noun] > hydrocarbon radicals > bivalent radicals
ethylene1853
ethylidene1859
propylidene1876
pentamethylene1887
vinylidene1898
isopropylidene1900
1900 E. F. Smith tr. V. von Richter Org. Chem. (ed. 3) II. 495 The condensation of the same oxime in the presence of ketones or aldehydes gives rise to isopropylidene and benzylidene methyl isoxazolons, (C4H3NO2):C(CH3)2[etc.].
1932 H. Pringsheim Chem. Monosaccharides & Polysaccharides ii. 31 Into the hexoses and pentoses there can be introduced two isopropylidene remainders.
1967 R. J. McIlroy Introd. Carbohydrate Chem. v. 52 This displacement of the ring has led to the employment of isopropylidene derivatives in the synthesis of reference compounds of the furanose type.
extracted from iso-comb. form
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