单词 | isoalloxazine |
释义 | > as lemmasisoalloxazine isoalloxazine n. Brit. /ˌʌɪsəʊəˈlɒksəziːn/ , U.S. /ˌaɪsoʊəˈlɑksəˌzin/ [allox- (in alloxan n.) + azine n.] the hypothetical tricyclic parent compound, C10H6N4O2, of the flavins, which has a structure formed of fused benzene, pyrazine, and pyrimidine nuclei and is known only as substituted derivatives.ΘΚΠ the world > matter > chemistry > organic chemistry > azines > [noun] azine1887 isoalloxazine1936 1936 Chem. Abstr. 30 4512 Isoalloxazines with a substituent, e.g., alkyl, cycloalkyl or aryl, in the 9-position are prepd. by condensing N-monosubstituted aromatic o-diamines with alloxan. 1953 J. S. Fruton & S. Simmonds Gen. Biochem. xiii. 320 In riboflavin, a sugar residue d-ribitol, is attached to a nitrogen atom of a heterocyclic nucleus, termed an isoalloxazine ring. 1968 I. L. Finar Org. Chem. (ed. 4) II. 556 It appears that isoalloxazine, the tautomer of alloxazine, does not exist as such; only when the hydrogen atom is substituted is the isoalloxazine form retained. < as lemmas |
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