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单词 hittorf transport number
释义

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Hittorf transport (or transference) number
Used attributively and occasionally in the possessive to denote various phenomena, pieces of apparatus, techniques, and concepts observed or invented by Hittorf, as Hittorf dark space = Crookes dark space; Hittorf method, a method of finding the transport numbers of ions in an electrolyte by measuring the change in concentration of the ions near the electrodes during electrolysis; Hittorf transport (or transference) number, a transport number as found by the Hittorf method.
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the world > matter > physics > electromagnetic radiation > electricity > electrolysis > [noun] > ion > current attributed to
Hittorf transport (or transference) number1892
transport number1897
the world > matter > physics > electromagnetic radiation > electricity > electrolysis > [noun] > ion > current attributed to > method of determining
Hittorf method1892
the world > matter > physics > electromagnetic radiation > electricity > discharge of electricity > [noun] > dark space at low pressure
Crookes layer1884
Crookes space1884
cathode dark space1914
Hittorf dark space1916
1892 T. O'C. Sloane Standard Electr. Dict. (1893) 289 Hittorf's solution, a solution sometimes used as a resistance. It is a solution of cadmium iodide in amylic alcohol.
1892 T. O'C. Sloane Standard Electr. Dict. (1893) 466 Hittorf's resistance, a high resistance, often a megohm, composed of Hittorf's solution.
1897 M. M. P. Muir tr. R. Lüpke Elem. Electro-chem. i. iii. 41 (heading) Hittorf's transport-numbers.
1909 Jrnl. Amer. Chem. Soc. 31 351 (heading) The relation between the true transference number and the Hittorf transference number.
1909 Jrnl. Amer. Chem. Soc. 31 351 The ordinary transference number (TH) for concentrated solutions, as obtained by the Hittorf method, is erroneous in cases where the ions are hydrated, since it is calculated on the assumption that the water remains stationary during the passage of the current.
1916 F. B. Pidduck Treat. Electr. xii. 487 The negative glow and the Hittorf dark space expand continually as the pressure is reduced.
1941 J. D. Cobine Gaseous Conductors viii. 213 Following the cathode glow is another dark space variously called the cathode dark space, the Crookes dark space, the Hittorf dark space.
1942 S. Glasstone Introd. Electrochem. vi. 114 Although the Hittorf method is simple in principle, accurate results are difficult to obtain.
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