单词 | anchimerically |
释义 | > as lemmasanchiˈmerically anchiˈmerically adv. by the participation of a neighbouring functional group or bond in the same molecule. ΘΚΠ the world > matter > chemistry > chemical structure or stereochemistry > [adverb] > characterized by functional groups trifunctionally1941 anchimerically1953 1953 Jrnl. Amer. Chem. Soc. 75 148/1 The rate constant of solvolysis with nucleophilic solvent participation exceeds kc more than does the anchimerically assisted ionization rate. 2007 Tetrahedron Lett. 48 4072/2 The mechanism through which this product was formed must presumably proceed via the formation of the expected anchimerically stabilized cation at the bridging carbon atom. < as lemmas |
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