单词 | disulphide |
释义 | disulphidedisulfiden. Chemistry. A compound in which two atoms of sulphur are united with another element or a radical, as carbon disulphide, CS2. †Formerly, a compound having one atom of sulphur united to two of another element, as disulphide of copper = cuprous sulphide, Cu2S. ΚΠ 1864 H. Watts Dict. Chem. II. 74 Hemisulphide of Copper, or Cuprous Sulphide, Cu4=Ccu2S, or Cu2S, also called Disulphide of copper.—Found native as Copper-glance. 1866 H. E. Roscoe Lessons Elem. Chem. xii. 109 When deposited from solution in carbonic di-sulphide, sulphur crystallizes in the ordinary natural or octahedral form. 1895 Edinb. Rev. Oct. 409 Carbon disulphide took it up more freely. Draft additions March 2020 disulphide bond n. a covalent linkage between two sulphur atoms, —S—S—, which cross-links polypeptide chains in the three-dimensional structures of some proteins; also called disulphide bridge.The sulphur atoms are provided by the thiol groups of the amino acid cysteine. ΚΠ 1934 Jrnl. Amer. Chem. Soc. 56 937/2 Cystine is reduced by sodium, in part, by sodium acting directly upon the disulfide bond. 2009 T. Shibamoto & L. Bjeldanes Introd. Food Toxicol. (ed. 2) vi. 140 Ricin is composed of two protein chains, A and B, linked by a disulfide bond. Draft additions March 2020 disulphide bridge n. = disulphide bond n. at Additions. ΚΠ 1932 Jrnl. Amer. Chem. Soc. 54 4396 It is thought also that where sulfhydryl groups do exist in a unit they combine with similar groups of other units to form aggregates held together by disulfide bridges and perhaps by other means. 1990 EMBO Jrnl. 9 2361/1 Hirudin consists of a polypeptide chain of 65 or 66 residues with three disulphide bridges. This entry has not yet been fully updated (first published 1897; most recently modified version published online March 2022). < n.1864 |
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