chemoselectiveadj.

Brit.

/ˌkiːməʊsᵻˈlɛktɪv/,

/ˌkɛməʊsᵻˈlɛktɪv/, U.S.

/ˌkimoʊsəˈlɛktɪv/,

/ˌkɛmoʊsəˈlɛktɪv/

Origin: Formed within English, by compounding. Etymons: chemo- comb. form, selective adj.

Etymology: < chemo- comb. form + selective adj.

Chemistry.

Of a chemical reaction or procedure: involving a particular functional group in preference to one or more others which are available.

ΚΠ

1976 Tetrahedron 32 926/2 Chemical transformations without the protection of other functional groups may conveniently be classified as being chemoselective or chemospecific.

1985 Science 22 Feb. 913/3 In defining strategies..to construct complex molecules we require synthetic methods that can..perform a wanted structural change and none other (that is, be chemoselective).

2004 W. Carruthers & I. Coldham Mod. Methods Org. Synthesis (ed. 4) i. 25 Chemoselective reduction of the ester group in the presence of the carboxylic amide..gave iridomyrmecin.

Derivatives

chemoseˈlectively adv. Chemistry in a chemoselective manner.

ΚΠ

1978 Tetrahedron Lett. No. 33. 3043 Methyl levulinate..can be allylated chemoselectively only at the keto group but not at the ester group to give a lactone.

2000 A. F. Parsons Introd. Free Radical Chem. vii. 152 Reaction of aryl bromide..with tributyltin hydride chemoselectively breaks the carbon-bromine bond to generate the reactive aryl radical.

This is a new entry (OED Third Edition, December 2008; most recently modified version published online March 2022).

单词	chemoselective
释义	chemoselectiveadj. Brit. /ˌkiːməʊsᵻˈlɛktɪv/, /ˌkɛməʊsᵻˈlɛktɪv/, U.S. /ˌkimoʊsəˈlɛktɪv/, /ˌkɛmoʊsəˈlɛktɪv/ Origin: Formed within English, by compounding. Etymons: chemo- comb. form, selective adj. Etymology: < chemo- comb. form + selective adj. Chemistry. Of a chemical reaction or procedure: involving a particular functional group in preference to one or more others which are available. ΚΠ 1976 Tetrahedron 32 926/2 Chemical transformations without the protection of other functional groups may conveniently be classified as being chemoselective or chemospecific. 1985 Science 22 Feb. 913/3 In defining strategies..to construct complex molecules we require synthetic methods that can..perform a wanted structural change and none other (that is, be chemoselective). 2004 W. Carruthers & I. Coldham Mod. Methods Org. Synthesis (ed. 4) i. 25 Chemoselective reduction of the ester group in the presence of the carboxylic amide..gave iridomyrmecin. Derivatives chemoseˈlectively adv. Chemistry in a chemoselective manner. ΚΠ 1978 Tetrahedron Lett. No. 33. 3043 Methyl levulinate..can be allylated chemoselectively only at the keto group but not at the ester group to give a lactone. 2000 A. F. Parsons Introd. Free Radical Chem. vii. 152 Reaction of aryl bromide..with tributyltin hydride chemoselectively breaks the carbon-bromine bond to generate the reactive aryl radical. This is a new entry (OED Third Edition, December 2008; most recently modified version published online March 2022). < adj.1976
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