| 释义 |
protonate, v. Chem.|ˈprəʊtəneɪt|
[f. proton + -ate3.]
a. trans. To transfer a proton to (a molecule, group, atom, etc.), a co-ordinate bond being formed to the proton.
b. intr. To receive a proton in this way. So ˈprotonated ppl. a., having received a proton; bonded to an additional proton; ˈprotonating vbl. n.
As used by Pitzer (quot. 1945), protonated had a slightly different, more restricted sense, being applied to the two bonds (each with a bridging hydrogen atom) which link the boron atoms in the electron-deficient compound diborane, B2H6.
1945K. S. Pitzer in Jrnl. Amer. Chem. Soc. LXVII. 1127/1 Let us call it a proton containing double bond or, shorter, a protonated double bond. 1951Jrnl. Amer. Chem. Soc. LXXIII. 3647/2 With the carbinols..the fact that one p-amino grouping was never protonated is consistent with the view that only one of the rings is involved in resonance interactions. 1958Ibid. LXXX. 3715/1 Compounds such as tri-p-aminophenylmethanol..when dissolved in sulfuric acid form stable carbonium ions in spite of the strong electron-withdrawing groups present in the form of protonated amino substituents. 1966Smith & Cristol Org. Chem. xlii. 795 Pyrrole..does protonate in the presence of very strong acids with the destruction of the aromatic sextet. 1969T. R. Blackburn Equilibrium ii. 66 Any acid stronger than the hydronium ion will simply protonate water molecules to produce an equal quantity of H3O+. 1972Cotton & Wilkinson Adv. Inorg. Chem. (ed. 3) v. 176 Even protonated carbonic acid, or more properly, the trihydroxycarbonium ion, C(OH)3+..has been observed in solutions of carbonates or bicarbonates in FSO3H-SbF5-SO2 solutions at -78°. Ibid. 182 Fluorosulfuric is one of the strongest of pure liquid acids. It is commonly used in presence of Sbf5 as a protonating system. 1975Nature 30 Oct. 823/2 Calculations..show that this spectral shift can be associated with the formation of the protonated C = N+ bond. |