| 释义 |
phosphonitrilic, a. Chem.|ˌfɒsfəʊnaɪˈtrɪlɪk|
[f. as prec. + -ic.]
Containing the phosphonitrile group, {b1}N{b2}P{b1}{btr1}{bbr1}. Cf. phosphazene.
1895H. N. Stokes in Amer. Chem. Jrnl. XVII. 278, (d) is a polymer of an acid N{b3}P(OH)2, which we may call phosphonitrilic acid. 1943Chem. Rev. XXXII. 119 The phosphonitrilic chlorides form as complete a polyhomologous series as is known in the realm of chemistry. Ibid. 122 The phosphonitrilic halides undergo reactions of hydrolysis to yield partially and completely hydroxylated products—the latter being known as the phosphonitrilic acids. 1956H. H. Sisler in Sneed & Brasted Comprehensive Inorg. Chem. V. i. ii. 134 All the phosphonitrilic chlorides, when heated to about 300°C, are converted to an elastic product, possessing many of the properties of rubber. 1974D. E. C. Corbridge Struct. Chem. Phosphorus xii. 333 Phosphonitrilic compounds, or phosphazenes, are characterized by the presence of the group P{b2}N{b1}. |