释义 |
peˈracetate Chem. [f. per-1 5 b + acetate.] †1. A compound of acetic acid with a base, containing a maximum proportion of the acid. Obs. peracetate of iron, old name of ferric acetate.
1836Brande Chem. (ed. 4) 1118 Peracetate of Iron may be obtained by digesting turnings and clippings of iron in acetic acid. 1864H. Spencer Biol. I. 20 Prof. Graham remarks of the peracetate of iron, that it may be made a source of soluble peroxide. 2. An ester or related derivative of peracetic acid.
1901Jrnl. Chem. Soc. LXXX. i. 308 Acetic anhydride furnishes an oily product, probably ethyl peracetate. 1949Chem. Rev. XLV. 8 Ethyl peracetate has been reported... This compound cannot be classed as a derivative of peracetic acid and ethyl alcohol, but rather as a derivative of acetic acid and ethyl hydroperoxide. 1967L. F. & M. A. Fieser Reagents for Org. Synthesis I. 790. The reaction may proceed through the hemiacetal peracetate. |