| 释义 |
ˈozonide
[-ide.]
1. (See quot. 1872.)
1867N. Syd. Soc. Retros. Med. 464 Ozonides, such as permanganate of potash and the persalts of iron, turn the resin blue. 1872C. B. Fox Ozone 11 Schönbein called those bodies containing Oxygen in a negatively active condition Ozonides.
2. a. [ad. G. ozonid (C. Harries 1904, in Ber. d. Deut. Chem. Ges. XXXVII. 840).] Any of the compounds containing the ring C{b1}O{b1}O{b1}C{b1}O , which are formed by the addition of ozone to olefinic double bonds and are explosive oils or amorphous solids.
1904Jrnl. Chem. Soc. LXXXVI. i. 361 The ozonides are mostly highly explosive. 1929R. A. Gortner Outl. Biochem. xxxi. 640 On treatment of the oleic acid ozonide with water, it decomposes into hydrogen peroxide, pelargonic acid, and azelaic acid semi-aldehyde. 1959E. L. Mascall Pi in the High 28 Though many facts that art. provides Re substances called Ozonides. 1968R. O. C. Norman Princ. Org. Synthesis xviii. 505 Lithium aluminium hydride reduces ozonides to alcohols.
b. The ion O3-, or a salt of this ion.
1949Chem. Abstr. XLIII. 4170 The compd. can be formulated K+, O3-, and termed K ozonide. 1962P. J. & B. Durrant Introd. Adv. Inorg. Chem. xxi. 799 The ozonide ion, (O{b1}O{b1}O)-, is present in potassium ozonide, KO3. 1966McGraw-Hill Encycl. Sci. & Technol. XII. 409/2 Sodium also forms an ozonide, NaO3, when ozone is passed into a solution of sodium in liquid ammonia. |