| 释义 |
metallocarborane, n. Chem.|mɪˌtæləʊˈkɑːbəreɪn|
[f. metallo- + carbon n. + borane n.]
A compound consisting of metal ions complexed with ligands containing carbon, boron, and hydrogen.
1969Inorg. Chem. VIII. 2080 (heading) Crystal structure of..a salt of a three-icosahedral-fragment metallocarborane. 1976Nature 11 Mar. 176/3 Although work on various metallocarboranes is reported, there is almost no coverage of carboranes per se. 1984Greenwood & Earnshaw Chem. of Elements (1986) vi. 212 Numerous variants are possible including the insertion of a second metal centre into an existing metallocarborane. 1987Inorg. Chem. XXVI. 3117/2 In the negative ion spectra, the parent group is the most intense in the spectrum (typical for metallocarboranes). |